Aquabis[N′-(2-hydroxybenzylidene)isonicotinohydrazide-κN]silver(I) nitrate
نویسندگان
چکیده
In the title compound, [Ag(C(13)H(11)N(3)O(2))(2)(H(2)O)]NO(3), two N atoms from two pyridine rings of two N'-(2-hydroxy-benzyl-idene)isonicotinohydrazide ligands coordinate to the Ag(I) atom, forming a nearly linear geometry with an N-Ag-N angle of 171.63 (6)°; a water O atom is located at the apical site, completing the T-shaped coordination. The crystal structure is stabilized by extensive O-H⋯O, O-H⋯N and N-H⋯O hydrogen bonding.
منابع مشابه
(2-Amino-4,6-dimethylpyrimidine-κN 1)(2-amino-4-methylpyrimidine-κN 1)silver(I) nitrate
Colourless crystals of the title compound, [Ag(C(5)H(7)N(3))(C(6)H(9)N(3))]NO(3), separated out of a solution of 2-amino-4-methyl-pyrimidine, 2-amino-4,6-dimethyl-pyrimidine and silver nitrate in water and methanol. The central Ag(I) ion is coordinated by two different N atoms in the aromatic rings of the ligands, with an N-Ag-N angle of 173.9 (2)°. The crystal structure is composed of two comp...
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متن کاملBis(2-phenyl-1H-imidazole-κN 3)silver(I) nitrate
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متن کاملBis(4-methyl-3,5-diphenyl-1H-pyrazole-κN 2)silver(I) nitrate
In the title complex, [Ag(C(16)H(14)N(2))(2)]NO(3), the geometry around the Ag(I) ion is T-shaped with two short Ag-N bonds to the pyrazole ligand and one long Ag-O bond to the nitrate anion. The crystal structure is stabilized by inter-molecular N-H⋯O, C-H⋯O and C-H⋯π inter-actions.
متن کاملBis[2-(1H-imidazol-2-yl-κN 3)-1H-imidazol-3-ium]silver(I) trinitrate
The synthesis of the title salt, [Ag(C(6)H(7)N(4))(2)](NO(3))(3), was carried out employing a 1:2 molar ratio of 2,2'-biimidazole and silver nitrate respectively. The cation has crystallographically-imposed C2 symmetry with the metal atom in an almost linear coordination environment [N-Ag-N = 177.01 (17)°]. The crystal structure displays N-H⋯O and C-H⋯O hydrogen-bonding inter-actions.
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عنوان ژورنال:
دوره 66 شماره
صفحات -
تاریخ انتشار 2010